A new Schiff base nickel(II) complex: {5,5′-dihydroxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol disolvate
نویسندگان
چکیده
The monomeric title nickel(II) complex of a salicylaldimine, [Ni(C(20)H(14)N(2)O(4))]·2CH(3)OH, was obtained by the reaction of 2,4-dihydroxy-benzaldehyde and 1,2-phenyl-enediamine with nickel(II) acetate. The Ni(II) atom is coordinated by two N atoms [Ni-N = 1.839 (2) Å] and two O atoms [Ni-O = 1.8253 (19) Å] in an approximately square-planar geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into a chain along [001].
منابع مشابه
{6,6′-Dimethoxy-2,2′-[4-bromo-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II) methanol solvate
In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetra-dentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent mol-ecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10....
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In the title compound, [Cu(C(20)H(14)N(2)O(4))]·2CH(3)OH, the Cu(II) ion is coordinated by two N [Cu-N = 1.933 (2) and 1.941 (2) Å] and two O [Cu-O = 1.890 (2) and 1.9038 (19) Å] atoms from the tetra-dentate Schiff base ligand 5,5'-dihydr-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphen-olate (L) in a distorted square-planar geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds l...
متن کامل{5,5′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)
In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom shows a square-planar geometry. The dihedral angles between the central benzene ring and the two outer rings are 4.79 (15) and 7.54 (15)°. In the crystal, mol-ecules are connected through inter-molecular C-H⋯O hydrogen bond, resulting in chains extending along the c axis. The crystal structure is further stabilized by i...
متن کامل{2,2′-[4-Chloro-5-methyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)
In the title complex, [Ni(C(21)H(15)ClN(2)O(2))], the Ni(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand in a distorted square geometry. The crystal packing exhibits short inter-molecular Ni⋯Ni distances of 3.273 (3) Å.
متن کامل{6,6′-Dimethoxy-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenolato}nickel(II)
In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom has a slightly distorted square-planar coordination environment. The dihedral angles between the central benzene ring and the two outer rings are 7.62 (16) and 9.78 (17)°. The crystal structure is stabilized by inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions with a centroid-centroid distance of 3.8218 (19) Å.
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